Technical documentation

US3282773

This invention relates to alpha-cyanoacrylate adhesive compositions and bonds formed therefrom. More particularly, our invention is concerned with adhesive formulations comprising monomeric esters of alpha-cyanoacrylic acid and vinyl aromatic compounds for bonding metallic or non-metallic surfaces to themselves or to each other and otherwise providing a superior bonded article.

EP0963420

A radiation-curable composition which includes a cyanoacrylate component or a cyanoacrylate-containing formulation; a metallocene component; and a polymerizingly effective amount of a photoinitiator to accelerate the rate of cure is provided.

WO2008085285

The present invention provides a cyanoacrylate composition comprising a cyanoacrylate component; and a core shell rubber component having a particle size in the range of 3 nm to 1,000 nm dispersed in a curable (meth)acrylate matrix.

US7390851

This invention relates to toughened cyanoacrylate compositions which exhibit improved peel strengths and fixture speeds. The toughened cyanoacrylate compositions include a toughening agent comprising poly(vinychloride-co-vinyl acetate) and poly(methylmethacrytlate).

WO2006048851

This invention relates to cyanoacrylate-containing compositions that exhibit at least one of improved shock resistance and bond strength, while demonstrating relative surface insensitivity with respect to establishing and maintaining fixture times that are on the order of comparable cyanoacrylate compositions without the added carboxylic acids, The compositions include, in addition to the cyanoacrylate component, certain carboxylic acids.

US4446282

The green strength of polymers produced by emulsion polymerization processes is improved through the use of carboxyl containing compounds. Specifically, the compounds are half esters of unsaturated dicarboxylic acids wherein the half ester moiety renders the carboxyl containing compound hydrophobic. As a result, carboxylic copolymers can be produced in emulsion polymerizations having a basic (pH.gtoreq.7.0) aqueous medium. Heretofore, use of carboxylic acids in emulsion polymerizations have been limited to acidic mediums.

US7687561

The present invention relates to toughened cyanoacrylate compositions.

US2776232

This invention relates to adhesive compositions particularly adapted for forming flexible adhesive bonds and is particularly concerned with adhesive compositions comprising a mixture of at least two different esters of alpha-cyanoacrylic acid.

US4440910

Disclosed are cyanoacrylate adhesive compositions containing elastomeric polymers as fillers. Preferred fillers are the acrylic rubbers. Filler concentration range from about 0.5-40% by weight of the composition. Beneficial results include improved toughness of the cured compositions, as measured by impact, peel and tensile strength properties, particularly after exposure elevated temperatures which would ordinarily severely degrade the adhesive strength.

US4196271

An adhesive composition comprising a 2-cyanoacrylate and at least one member selected from the group consisting of substituted or unsubstituted aliphatic carboxylic acids having three or more carboxyl groups, anhydrides thereof, partial esters thereof, aromatic polycarboxylic acids having three or more carboxyl groups and anhydrides thereof. This composition has a high impact strength, is suitable for bonding metallic substrates to one another and is also excellent in resistance to heat, weather, and water.

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