The invention relates to a method of applying a nailwrap to a human nail. The method includes depositing an effective amount of a polymerization catalyst on the nailwrap, placing the nailwrap on a portion of the nail, and depositing a first layer of a monomer over the nailwrap to simulate a human nail. By depositing the polymerization catalyst on the nailwrap, polymerization of the monomer occurs from the bulk, i.e., the surface of the human nail, and proceeds to the surface of the artificial nail structure.