The effect the curing conditions on the properties of adhesive joints formed using cyanoacrylate-based adhesives is investigated. The temperature dependences of relative rigidity and mechanical loss tangent are studied by torque analysis for poly(ethyl-, allyl-, allyloxyethyl-, allyloxyisopropyl-, propargyloxyethyl-, and propargyl-) cyanoacrylates after their thermal treatment in the temperature range of 20–250°C. The glass transition parameters of polycyanoacrylates and the dependence of the curing intensity on the structure of initial monomers and polymers are determined.