Cement

Glass ionomer cement (GIC) has been successfully used in dental field for more than 40 years. Despite numerous advantages of GIC, low bond strength and slow setting rate limited conventional GICs for use only at low stress-bearing areas. To improve bond strength to tooth, two kinds of cyanoacrylates such as ethyl 2-cyanoacrylate (EC) and allyl 2-cyanoacrylate (AC) were added in a commercial GIC. Changes in setting time of cyanoacrylate-modified GICs (CMGICs) according to the concentration of cyanoacrylates and/or p-toluene sulfonic acid (TSA) was investigated using a rheometer.

An adhesive cement is prepared by coating an aluminosilicate glass ionomer with an acid polymerization inhibitor of pKa between 2-3.5, and then mixing the treated glass with cyanoacrylate monomer and water. The glass is treated by dissolving the acid, typically tartaric, tartronic, malic, maleic or mellitic acid in methanol and adding the glass powder to form a slurry, then evaporating the methanol.